﻿<?xml version="1.0" encoding="utf-8"?>
<srm_settings format_version="3.7" software_version="Skyline (64-bit) 3.7.0.10940">
  <settings_summary name="Default">
    <peptide_settings>
      <enzyme name="Trypsin" cut="KR" no_cut="P" sense="C" />
      <digest_settings max_missed_cleavages="0" />
      <peptide_prediction use_measured_rts="true" measured_rt_window="2" use_spectral_library_drift_times="false" spectral_library_drift_times_peak_width_calc_type="resolving_power" spectral_library_drift_times_resolving_power="0" spectral_library_drift_times_width_at_dt_zero="0" spectral_library_drift_times_width_at_dt_max="0" />
      <peptide_filter start="25" min_length="6" max_length="15" auto_select="true">
        <peptide_exclusions>
          <exclusion name="Cys" regex="[C]" />
          <exclusion name="Met" regex="[M]" />
        </peptide_exclusions>
      </peptide_filter>
      <peptide_libraries pick="both" />
      <peptide_modifications max_variable_mods="3" max_neutral_losses="1">
        <static_modifications>
          <static_modification name="Carbamidomethyl Cysteine" aminoacid="C" formula="C2H3ON" />
          <static_modification name="Oxidation (M)" aminoacid="M" formula="O" unimod_id="35">
            <potential_loss formula="H4COS" massdiff_monoisotopic="63.998285" massdiff_average="64.10701" />
          </static_modification>
        </static_modifications>
        <heavy_modifications>
          <static_modification name="Label:13C15N" label_13C="true" label_15N="true" explicit_decl="true" />
        </heavy_modifications>
      </peptide_modifications>
    </peptide_settings>
    <transition_settings>
      <transition_prediction precursor_mass_type="Monoisotopic" fragment_mass_type="Monoisotopic" optimize_by="Transition">
        <predict_collision_energy name="TTOF 5600" step_size="2" step_count="3">
          <regression_ce charge="2" slope="0.044" intercept="5" />
          <regression_ce charge="3" slope="0.058" intercept="4" />
        </predict_collision_energy>
        <predict_declustering_potential name="ABI" step_size="1" step_count="5" slope="0.0729" intercept="31.117" />
      </transition_prediction>
      <transition_filter precursor_charges="2,3" product_charges="1" fragment_types="y,b" fragment_range_first="m/z &gt; precursor" fragment_range_last="3 ions" precursor_mz_window="0" auto_select="true">
        <measured_ion name="N-terminal to Proline" cut="P" sense="N" min_length="3" />
      </transition_filter>
      <transition_libraries ion_match_tolerance="0.5" ion_count="6" pick_from="all" />
      <transition_integration />
      <transition_instrument min_mz="50" max_mz="1250" mz_match_tolerance="0.055" />
      <transition_full_scan acquisition_method="Targeted" product_mass_analyzer="tof" product_res="10000" precursor_isotopes="Percent" precursor_isotope_filter="20" precursor_mass_analyzer="tof" precursor_res="20000" retention_time_filter_type="ms2_ids" retention_time_filter_length="5">
        <isotope_enrichments name="Default">
          <atom_percent_enrichment symbol="H'">0.98</atom_percent_enrichment>
          <atom_percent_enrichment symbol="C'">0.995</atom_percent_enrichment>
          <atom_percent_enrichment symbol="N'">0.995</atom_percent_enrichment>
          <atom_percent_enrichment symbol="O&quot;">0.99</atom_percent_enrichment>
          <atom_percent_enrichment symbol="O'">0.99</atom_percent_enrichment>
        </isotope_enrichments>
      </transition_full_scan>
    </transition_settings>
    <data_settings document_guid="5e6183aa-64aa-4a52-b3d5-7bc65adaa096" />
    <measured_results time_normal_area="true">
      <replicate name="0 mM in matrix 2-1">
        <sample_file id="_0_mM_in_matrix_2-1_f0" file_path="C:\Data PP\MRM\TT5600 results\goto project\2019_04_30\0 mM in matrix 2-1.wiff" sample_name="0 mM in matrix 2-1" acquired_time="2019-05-03T15:11:19" modified_time="2019-05-03T07:26:26">
          <instrument_info_list>
            <instrument_info>
              <model>Applied Biosystems instrument model</model>
            </instrument_info>
          </instrument_info_list>
        </sample_file>
      </replicate>
      <replicate name="0.5 mM in matrix 2-1">
        <sample_file id="_0.5_mM_in_matrix_2-1_f0" file_path="C:\Data PP\MRM\TT5600 results\goto project\2019_04_30\0.5 mM in matrix 2-1.wiff" sample_name="0.5 mM in matrix 2-1" acquired_time="2019-05-03T17:25:06" modified_time="2019-05-03T09:40:10">
          <instrument_info_list>
            <instrument_info>
              <model>Applied Biosystems instrument model</model>
            </instrument_info>
          </instrument_info_list>
        </sample_file>
      </replicate>
      <replicate name="1 mM in matrix 2-1">
        <sample_file id="_1_mM_in_matrix_2-1_f0" file_path="C:\Data PP\MRM\TT5600 results\goto project\2019_04_30\1 mM in matrix 2-1.wiff" sample_name="1 mM in matrix 2-1" acquired_time="2019-05-03T19:38:48" modified_time="2019-05-03T11:53:53">
          <instrument_info_list>
            <instrument_info>
              <model>Applied Biosystems instrument model</model>
            </instrument_info>
          </instrument_info_list>
        </sample_file>
      </replicate>
      <replicate name="2.5 mM in matrix 2-1">
        <sample_file id="_2.5_mM_in_matrix_2-1_f0" file_path="C:\Data PP\MRM\TT5600 results\goto project\2019_04_30\2.5 mM in matrix 2-1.wiff" sample_name="2.5 mM in matrix 2-1" acquired_time="2019-05-03T21:52:28" modified_time="2019-05-03T14:07:35">
          <instrument_info_list>
            <instrument_info>
              <model>Applied Biosystems instrument model</model>
            </instrument_info>
          </instrument_info_list>
        </sample_file>
      </replicate>
      <replicate name="10 mM in matrix 2-1">
        <sample_file id="_10_mM_in_matrix_2-1_f0" file_path="C:\Data PP\MRM\TT5600 results\goto project\2019_04_30\10 mM in matrix 2-1.wiff" sample_name="10 mM in matrix 2-1" acquired_time="2019-05-04T00:06:14" modified_time="2019-05-03T16:21:18">
          <instrument_info_list>
            <instrument_info>
              <model>Applied Biosystems instrument model</model>
            </instrument_info>
          </instrument_info_list>
        </sample_file>
      </replicate>
      <replicate name="50 mM in matrix 2-1">
        <sample_file id="_50_mM_in_matrix_2-1_f0" file_path="C:\Data PP\MRM\TT5600 results\goto project\2019_04_30\50 mM in matrix 2-1.wiff" sample_name="50 mM in matrix 2-1" acquired_time="2019-05-04T02:19:56" modified_time="2019-05-03T18:35:02">
          <instrument_info_list>
            <instrument_info>
              <model>Applied Biosystems instrument model</model>
            </instrument_info>
          </instrument_info_list>
        </sample_file>
      </replicate>
      <replicate name="75 mM in matrix 2-1">
        <sample_file id="_75_mM_in_matrix_2-1_f0" file_path="C:\Data PP\MRM\TT5600 results\goto project\2019_04_30\75 mM in matrix 2-1.wiff" sample_name="75 mM in matrix 2-1" acquired_time="2019-05-04T04:33:42" modified_time="2019-05-03T20:48:48">
          <instrument_info_list>
            <instrument_info>
              <model>Applied Biosystems instrument model</model>
            </instrument_info>
          </instrument_info_list>
        </sample_file>
      </replicate>
      <replicate name="100 mM in matrix 2-1">
        <sample_file id="_100_mM_in_matrix_2-1_f0" file_path="C:\Data PP\MRM\TT5600 results\goto project\2019_04_30\100 mM in matrix 2-1.wiff" sample_name="100 mM in matrix 2-1" acquired_time="2019-05-04T06:47:29" modified_time="2019-05-03T23:02:35">
          <instrument_info_list>
            <instrument_info>
              <model>Applied Biosystems instrument model</model>
            </instrument_info>
          </instrument_info_list>
        </sample_file>
      </replicate>
      <replicate name="0 mM in matrix 2-2">
        <sample_file id="_0_mM_in_matrix_2-2_f0" file_path="C:\Data PP\MRM\TT5600 results\goto project\2019_04_30\0 mM in matrix 2-2.wiff" sample_name="0 mM in matrix 2-2" acquired_time="2019-05-04T11:03:32" modified_time="2019-05-04T03:18:36">
          <instrument_info_list>
            <instrument_info>
              <model>Applied Biosystems instrument model</model>
            </instrument_info>
          </instrument_info_list>
        </sample_file>
      </replicate>
      <replicate name="0.5 mM in matrix 2-2">
        <sample_file id="_0.5_mM_in_matrix_2-2_f0" file_path="C:\Data PP\MRM\TT5600 results\goto project\2019_04_30\0.5 mM in matrix 2-2.wiff" sample_name="0.5 mM in matrix 2-2" acquired_time="2019-05-04T13:17:15" modified_time="2019-05-04T05:32:20">
          <instrument_info_list>
            <instrument_info>
              <model>Applied Biosystems instrument model</model>
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          </instrument_info_list>
        </sample_file>
      </replicate>
      <replicate name="1 mM in matrix 2-2">
        <sample_file id="_1_mM_in_matrix_2-2_f0" file_path="C:\Data PP\MRM\TT5600 results\goto project\2019_04_30\1 mM in matrix 2-2.wiff" sample_name="1 mM in matrix 2-2" acquired_time="2019-05-04T15:30:59" modified_time="2019-05-04T07:46:05">
          <instrument_info_list>
            <instrument_info>
              <model>Applied Biosystems instrument model</model>
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        </sample_file>
      </replicate>
      <replicate name="2.5 mM in matrix 2-2">
        <sample_file id="_2.5_mM_in_matrix_2-2_f0" file_path="C:\Data PP\MRM\TT5600 results\goto project\2019_04_30\2.5 mM in matrix 2-2.wiff" sample_name="2.5 mM in matrix 2-2" acquired_time="2019-05-04T17:44:47" modified_time="2019-05-04T09:59:53">
          <instrument_info_list>
            <instrument_info>
              <model>Applied Biosystems instrument model</model>
            </instrument_info>
          </instrument_info_list>
        </sample_file>
      </replicate>
      <replicate name="10 mM in matrix 2-2">
        <sample_file id="_10_mM_in_matrix_2-2_f0" file_path="C:\Data PP\MRM\TT5600 results\goto project\2019_04_30\10 mM in matrix 2-2.wiff" sample_name="10 mM in matrix 2-2" acquired_time="2019-05-04T19:58:32" modified_time="2019-05-04T12:13:39">
          <instrument_info_list>
            <instrument_info>
              <model>Applied Biosystems instrument model</model>
            </instrument_info>
          </instrument_info_list>
        </sample_file>
      </replicate>
      <replicate name="50 mM in matrix 2-2">
        <sample_file id="_50_mM_in_matrix_2-2_f0" file_path="C:\Data PP\MRM\TT5600 results\goto project\2019_04_30\50 mM in matrix 2-2.wiff" sample_name="50 mM in matrix 2-2" acquired_time="2019-05-04T22:12:21" modified_time="2019-05-04T14:27:25">
          <instrument_info_list>
            <instrument_info>
              <model>Applied Biosystems instrument model</model>
            </instrument_info>
          </instrument_info_list>
        </sample_file>
      </replicate>
      <replicate name="75 mM in matrix 2-2">
        <sample_file id="_75_mM_in_matrix_2-2_f0" file_path="C:\Data PP\MRM\TT5600 results\goto project\2019_04_30\75 mM in matrix 2-2.wiff" sample_name="75 mM in matrix 2-2" acquired_time="2019-05-05T00:26:04" modified_time="2019-05-04T16:41:07">
          <instrument_info_list>
            <instrument_info>
              <model>Applied Biosystems instrument model</model>
            </instrument_info>
          </instrument_info_list>
        </sample_file>
      </replicate>
      <replicate name="100 mM in matrix 2-2">
        <sample_file id="_100_mM_in_matrix_2-2_f0" file_path="C:\Data PP\MRM\TT5600 results\goto project\2019_04_30\100 mM in matrix 2-2.wiff" sample_name="100 mM in matrix 2-2" acquired_time="2019-05-05T02:39:50" modified_time="2019-05-04T18:54:57">
          <instrument_info_list>
            <instrument_info>
              <model>Applied Biosystems instrument model</model>
            </instrument_info>
          </instrument_info_list>
        </sample_file>
      </replicate>
      <replicate name="0 mM in matrix 2-3">
        <sample_file id="_0_mM_in_matrix_2-3_f0" file_path="C:\Data PP\MRM\TT5600 results\goto project\2019_04_30\0 mM in matrix 2-3.wiff" sample_name="0 mM in matrix 2-3" acquired_time="2019-05-05T06:55:57" modified_time="2019-05-04T23:11:04">
          <instrument_info_list>
            <instrument_info>
              <model>Applied Biosystems instrument model</model>
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        </sample_file>
      </replicate>
      <replicate name="0.5 mM in matrix 2-3">
        <sample_file id="_0.5_mM_in_matrix_2-3_f0" file_path="C:\Data PP\MRM\TT5600 results\goto project\2019_04_30\0.5 mM in matrix 2-3.wiff" sample_name="0.5 mM in matrix 2-3" acquired_time="2019-05-05T09:09:44" modified_time="2019-05-05T01:24:50">
          <instrument_info_list>
            <instrument_info>
              <model>Applied Biosystems instrument model</model>
            </instrument_info>
          </instrument_info_list>
        </sample_file>
      </replicate>
      <replicate name="1 mM in matrix 2-3">
        <sample_file id="_1_mM_in_matrix_2-3_f0" file_path="C:\Data PP\MRM\TT5600 results\goto project\2019_04_30\1 mM in matrix 2-3.wiff" sample_name="1 mM in matrix 2-3" acquired_time="2019-05-05T11:23:29" modified_time="2019-05-05T03:38:34">
          <instrument_info_list>
            <instrument_info>
              <model>Applied Biosystems instrument model</model>
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        </sample_file>
      </replicate>
      <replicate name="2.5 mM in matrix 2-3">
        <sample_file id="_2.5_mM_in_matrix_2-3_f0" file_path="C:\Data PP\MRM\TT5600 results\goto project\2019_04_30\2.5 mM in matrix 2-3.wiff" sample_name="2.5 mM in matrix 2-3" acquired_time="2019-05-05T13:37:14" modified_time="2019-05-05T05:52:20">
          <instrument_info_list>
            <instrument_info>
              <model>Applied Biosystems instrument model</model>
            </instrument_info>
          </instrument_info_list>
        </sample_file>
      </replicate>
      <replicate name="10 mM in matrix 2-3">
        <sample_file id="_10_mM_in_matrix_2-3_f0" file_path="C:\Data PP\MRM\TT5600 results\goto project\2019_04_30\10 mM in matrix 2-3.wiff" sample_name="10 mM in matrix 2-3" acquired_time="2019-05-05T15:51:01" modified_time="2019-05-05T08:06:04">
          <instrument_info_list>
            <instrument_info>
              <model>Applied Biosystems instrument model</model>
            </instrument_info>
          </instrument_info_list>
        </sample_file>
      </replicate>
      <replicate name="50 mM in matrix 2-3">
        <sample_file id="_50_mM_in_matrix_2-3_f0" file_path="C:\Data PP\MRM\TT5600 results\goto project\2019_04_30\50 mM in matrix 2-3.wiff" sample_name="50 mM in matrix 2-3" acquired_time="2019-05-05T18:04:43" modified_time="2019-05-05T10:19:49">
          <instrument_info_list>
            <instrument_info>
              <model>Applied Biosystems instrument model</model>
            </instrument_info>
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        </sample_file>
      </replicate>
      <replicate name="75 mM in matrix 2-3">
        <sample_file id="_75_mM_in_matrix_2-3_f0" file_path="C:\Data PP\MRM\TT5600 results\goto project\2019_04_30\75 mM in matrix 2-3.wiff" sample_name="75 mM in matrix 2-3" acquired_time="2019-05-05T20:18:28" modified_time="2019-05-05T12:33:32">
          <instrument_info_list>
            <instrument_info>
              <model>Applied Biosystems instrument model</model>
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        </sample_file>
      </replicate>
      <replicate name="100 mM in matrix 2-3">
        <sample_file id="_100_mM_in_matrix_2-3_f0" file_path="C:\Data PP\MRM\TT5600 results\goto project\2019_04_30\100 mM in matrix 2-3.wiff" sample_name="100 mM in matrix 2-3" acquired_time="2019-05-05T22:32:12" modified_time="2019-05-05T14:47:16">
          <instrument_info_list>
            <instrument_info>
              <model>Applied Biosystems instrument model</model>
            </instrument_info>
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    </measured_results>
  </settings_summary>
  <peptide_list label_name="Angioensin 1-9, 1-7" websearch_status="X" auto_manage_children="false">
    <peptide auto_manage_children="false" sequence="DRVYIHPFH" modified_sequence="DRVYIHPFH" calc_neutral_pep_mass="1182.593427" num_missed_cleavages="1" avg_measured_retention_time="16.3459053">
      <explicit_modifications>
        <explicit_heavy_modifications>
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      <peptide_results>
        <peptide_result replicate="0 mM in matrix 2-1" peak_count_ratio="1" retention_time="15.93985" />
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        <peptide_result replicate="1 mM in matrix 2-1" peak_count_ratio="1" retention_time="16.19505" />
        <peptide_result replicate="2.5 mM in matrix 2-1" peak_count_ratio="1" retention_time="16.32263" />
        <peptide_result replicate="10 mM in matrix 2-1" peak_count_ratio="1" retention_time="16.35455" />
        <peptide_result replicate="50 mM in matrix 2-1" peak_count_ratio="1" retention_time="16.32265" />
        <peptide_result replicate="75 mM in matrix 2-1" peak_count_ratio="1" retention_time="16.29075" />
        <peptide_result replicate="100 mM in matrix 2-1" peak_count_ratio="1" retention_time="16.29075" />
        <peptide_result replicate="0 mM in matrix 2-2" peak_count_ratio="1" retention_time="16.38643" />
        <peptide_result replicate="0.5 mM in matrix 2-2" peak_count_ratio="1" retention_time="16.41835" />
        <peptide_result replicate="1 mM in matrix 2-2" peak_count_ratio="1" retention_time="16.32263" />
        <peptide_result replicate="2.5 mM in matrix 2-2" peak_count_ratio="1" retention_time="16.38645" />
        <peptide_result replicate="10 mM in matrix 2-2" peak_count_ratio="1" retention_time="16.25885" />
        <peptide_result replicate="50 mM in matrix 2-2" peak_count_ratio="1" retention_time="16.32263" />
        <peptide_result replicate="75 mM in matrix 2-2" peak_count_ratio="1" retention_time="16.35455" />
        <peptide_result replicate="100 mM in matrix 2-2" peak_count_ratio="1" retention_time="16.3226662" />
        <peptide_result replicate="0 mM in matrix 2-3" peak_count_ratio="1" retention_time="16.35455" />
        <peptide_result replicate="0.5 mM in matrix 2-3" peak_count_ratio="1" retention_time="16.51403" />
        <peptide_result replicate="1 mM in matrix 2-3" peak_count_ratio="1" retention_time="16.45025" />
        <peptide_result replicate="2.5 mM in matrix 2-3" peak_count_ratio="1" retention_time="16.48213" />
        <peptide_result replicate="10 mM in matrix 2-3" peak_count_ratio="1" retention_time="16.54595" />
        <peptide_result replicate="50 mM in matrix 2-3" peak_count_ratio="1" retention_time="16.41835" />
        <peptide_result replicate="75 mM in matrix 2-3" peak_count_ratio="1" retention_time="16.35455" />
        <peptide_result replicate="100 mM in matrix 2-3" peak_count_ratio="1" retention_time="16.48215" />
      </peptide_results>
      <precursor charge="3" calc_neutral_mass="1182.593427" precursor_mz="395.205085" auto_manage_children="false" collision_energy="26.921895" declustering_potential="59.927451" modified_sequence="DRVYIHPFH">
        <precursor_results>
          <precursor_peak replicate="0 mM in matrix 2-1" peak_count_ratio="1" retention_time="15.93985" start_time="15.78035" end_time="16.06745" fwhm="0.08049089" area="6973.782" background="236.783188" height="599.1668" mass_error_ppm="-2.2147994" truncated="0" identified="false" user_set="TRUE" />
          <precursor_peak replicate="0.5 mM in matrix 2-1" peak_count_ratio="1" retention_time="16.22695" start_time="16.03555" end_time="16.38645" fwhm="0.09534296" area="12118.335" background="384.367218" height="864.4175" mass_error_ppm="4.305816" truncated="0" identified="false" user_set="TRUE" />
          <precursor_peak replicate="1 mM in matrix 2-1" peak_count_ratio="1" retention_time="16.19505" start_time="16.00365" end_time="16.38645" fwhm="0.08569801" area="22466.68" background="560.4409" height="1894.498" mass_error_ppm="2.586446" truncated="0" identified="false" user_set="TRUE" />
          <precursor_peak replicate="2.5 mM in matrix 2-1" peak_count_ratio="1" retention_time="16.32263" start_time="16.16313" end_time="16.48213" fwhm="0.09534101" area="55613.27" background="191.402435" height="4409.98" mass_error_ppm="4.94537735" truncated="0" identified="false" user_set="TRUE" />
          <precursor_peak replicate="10 mM in matrix 2-1" peak_count_ratio="1" retention_time="16.35455" start_time="16.16315" end_time="16.51405" fwhm="0.09267192" area="228572.641" background="27.02155" height="17807.72" mass_error_ppm="5.514008" truncated="0" identified="false" user_set="TRUE" />
          <precursor_peak replicate="50 mM in matrix 2-1" peak_count_ratio="1" retention_time="16.32265" start_time="16.13125" end_time="16.48215" fwhm="0.09878534" area="1087898.88" background="612.477539" height="77365.84" mass_error_ppm="4.1512866" truncated="0" identified="false" user_set="TRUE" />
          <precursor_peak replicate="75 mM in matrix 2-1" peak_count_ratio="1" retention_time="16.29075" start_time="16.09935" end_time="16.45025" fwhm="0.09829858" area="1579446" background="394.929565" height="111309.5" mass_error_ppm="8.02751" truncated="0" identified="false" user_set="TRUE" />
          <precursor_peak replicate="100 mM in matrix 2-1" peak_count_ratio="1" retention_time="16.29075" start_time="16.16315" end_time="16.48215" fwhm="0.09946281" area="2065288.25" background="530.4814" height="137158.9" mass_error_ppm="3.7703824" truncated="0" identified="false" user_set="TRUE" />
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            <transition_peak replicate="75 mM in matrix 2-3" mass_error_ppm="11.7" retention_time="16.35455" start_time="16.19505" end_time="16.54595" area="665858" background="240.9144" height="94523.73" fwhm="0.1094435" truncated="false" identified="false" rank="1" points_across="0" user_set="TRUE" />
            <transition_peak replicate="100 mM in matrix 2-3" mass_error_ppm="9.4" retention_time="16.48215" start_time="16.29075" end_time="16.64165" area="855617.8" background="54.58794" height="132390.8" fwhm="0.100012" truncated="false" identified="false" rank="1" points_across="0" user_set="TRUE" />
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            <transition_peak replicate="100 mM in matrix 2-3" mass_error_ppm="4.3" retention_time="16.48215" start_time="16.29075" end_time="16.64165" area="123233" background="290.0034" height="19390.08" fwhm="0.09714203" truncated="false" identified="false" rank="3" points_across="0" user_set="TRUE" />
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            <transition_peak replicate="0 mM in matrix 2-2" mass_error_ppm="-12.3" retention_time="13.45833" start_time="13.36263" end_time="14.12823" area="408.4865" background="323.4756" height="18.59685" fwhm="0.04774404" truncated="false" identified="false" rank="2" points_across="0" user_set="TRUE" />
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            <transition_peak replicate="1 mM in matrix 2-3" mass_error_ppm="3.3" retention_time="14.12825" start_time="13.33075" end_time="14.28775" area="3629.786" background="1089.625" height="363.5713" fwhm="0.1346362" truncated="false" identified="false" rank="2" points_across="0" user_set="TRUE" />
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            <transition_peak replicate="10 mM in matrix 2-3" mass_error_ppm="6.9" retention_time="14.12825" start_time="13.33075" end_time="14.28775" area="46488.04" background="1335.522" height="4639.948" fwhm="0.132695" truncated="false" identified="false" rank="2" points_across="0" user_set="TRUE" />
            <transition_peak replicate="50 mM in matrix 2-3" mass_error_ppm="11.6" retention_time="14.00065" start_time="13.17125" end_time="14.19205" area="215045.2" background="1481.087" height="17881.07" fwhm="0.1473675" truncated="false" identified="false" rank="2" points_across="0" user_set="TRUE" />
            <transition_peak replicate="75 mM in matrix 2-3" mass_error_ppm="14.9" retention_time="14.03255" start_time="13.42645" end_time="14.22395" area="302465.625" background="5964.817" height="26469.48" fwhm="0.143978223" truncated="false" identified="false" rank="2" points_across="0" user_set="FALSE" />
            <transition_peak replicate="100 mM in matrix 2-3" mass_error_ppm="10.4" retention_time="14.09635" start_time="13.36265" end_time="14.28775" area="406612.4" background="5544.299" height="32886.0938" fwhm="0.161654487" truncated="false" identified="false" rank="2" points_across="0" user_set="FALSE" />
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            <transition_peak replicate="50 mM in matrix 2-3" mass_error_ppm="7.3" retention_time="14.00065" start_time="13.17125" end_time="14.19205" area="64245.71" background="369.9512" height="5582.312" fwhm="0.1436897" truncated="false" identified="false" rank="3" points_across="0" user_set="TRUE" />
            <transition_peak replicate="75 mM in matrix 2-3" mass_error_ppm="9.1" retention_time="14.03255" start_time="13.42645" end_time="14.22395" area="58476.33" background="1966.05139" height="5484.283" fwhm="0.137826532" truncated="false" identified="false" rank="3" points_across="0" user_set="FALSE" />
            <transition_peak replicate="100 mM in matrix 2-3" mass_error_ppm="4.3" retention_time="14.09635" start_time="13.36265" end_time="14.28775" area="59485.25" background="1754.80847" height="5371.816" fwhm="0.153761163" truncated="false" identified="false" rank="3" points_across="0" user_set="FALSE" />
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        <transition fragment_type="b" fragment_ordinal="5" calc_neutral_mass="656.35213" product_charge="1" cleavage_aa="I" loss_neutral_mass="0">
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